Process for producing organopolysiloxane with high polymerizatio

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 34, 528 38, C08G 7708

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active

054497353

ABSTRACT:
Organopolysiloxanes having a silanol group at both terminal ends of molecular chain thereof are brought into condensation reaction with each other in the presence of a silane or siloxane having at least two dialkylaminosilyl groups per molecule as a condensation catalyst and a triorganosilanol or other endblocking agent, to lengthen the chain of the organopolysiloxane under reaction, whereby a triorganosilyl-endblocked organopolysiloxane with a high polymerization degree is obtained. The process yields a triorganosilyl-endblocked high-polymerization-degree organopolysiloxane while effectively suppressing or preventing the formation of low-molecular-weight siloxanes.

REFERENCES:
patent: 4683251 (1987-07-01), Mikami
patent: 4792596 (1988-12-01), Ottinger et al.
patent: 5109094 (1992-04-01), Rees et al.
patent: 5173558 (1992-12-01), Hansen
Zeigler et al. Silicon-Based Polymer Chemistry 1990, pp. 84-85.

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