Process for producing organic thin films

Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Forming nonmetal coating

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205162, C25D 902

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active

051356198

ABSTRACT:
A process for producing an organic thin film comprising solubilizing a hydrophobic organic substance with a surfactant containing a ferrocene compound in an aqueous medium to form a micelle solution, and electrolyzing the micelle solution to form a thin film of the hydrophobic organic substance on an electrode. The ferrocene compound has the formula: ##STR1## G is hydrogen, methyl or ethyl, R.sup.4 is hydrogen, methyl or ethyl,

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Journal of the American Chemical Society, vol. 109, 1987, pp. 5881-5883, American Chemical Society; K. Hoshino et al: "Electrochemical formation of an organic thin film by disruption of micelles".
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Chemistry Letters, No. 7, Jul. 1987, pp. 1439-1442, The Chemical Society of Japan; K. Hoshino et al.: "Electrochemical formation of thin film of viologen by disruption of micelles".
Chemical Abstracts, vol. 104, 1986, p. 533, abstract no 50983j, Columbus, Ohio, US; & JP-A-60 188 394 (Kawaken Fine Chemicals Co., Ltd) Sep. 25, 1985.
Chemical Abstracts, vol. 94, 1981, p. 741, abstract no. 84260m, Columbus, Ohio, US; M. Salisova et al.: "Attempts on internal Michael addition of the 1-(omega-anisoylalkyl)-1'-cinnamoylferrocenes", & Acta Fac. Rerum Nat. Univ. Comenianae, Chim. 1980, 28, 103-26.
Chemistry Letters, No. 4, Apr. 1988, pp. 693-696, The Chemical Society of Japan, T. Saji: "Electrochemical formation of a phthalocyanine thin film by disruption of micellar aggregates".
PCT Publication No. WO 89/01939 dated Sep. 3, 1989, Ferrocene Derivatives, Surfactants Containing Same, and Process for Producing Thin Organic with English language Abstract.

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