Process for producing optically active dichloropropanol using mi

Details Process for producing optically active dichloropropanol using mi Process for producing optically active dichloropropanol using mi

1986-06-02

1989-06-20

Warden, Robert J.

Chemistry: molecular biology and microbiology

Micro-organism, per se ; compositions thereof; proces of...

Bacteria or actinomycetales; media therefor

435157, 435280, 435874, C12R 138, C12P 4100, C12P 704

Patent

active

048409073

ABSTRACT:
A process for producing optically active dichloropropanol, which comprises cultivating an R-(+)-2,3-dichloro-1-propanol-assimilating strain belonging to the genus Pseudomonas in a culture medium containing racemate 2,3-dichloro-1-propanol, and recovering optical isomer S-(-)-2,3-dichloro-1-propanol from the culture broth, and a process for producing optically active epichlorohydrin, which comprises reacting the optical isomer S-(-)-2,3-dichloro-1-propanol obtained by the aforesaid process with an alkali.

REFERENCES:
patent: 4204044 (1980-05-01), Suhara et al.
Cambou et al., J. Am. Chem. Soc., 106:2687-2692 (1984).
Ellis et al., J. Chem. Soc. Chem. Commun., 1984, 1600-1602.
Iriuchijima et al., Agric. Biol. Chem., 46(6):1593-1597 (1982).
Baldwin et al., J. Org. Chem., 43(25):4876-4878 (1978).
Chemical Abstracts, 98, 104113d, 1983.
Chemical Abstracts, 105, 151578g, 1986.

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