Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1985-10-07
1988-02-16
Schofer, Joseph L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
502127, 526128, 526140, 526141, 526142, 526351, 526352, C08F 446, C08F 452, C08F 1002, C08F 1006
Patent
active
047256567
ABSTRACT:
A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that
(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si-O-C or Si-N-C bond, and
(2) said electron donor in the catalyst component (A) is selected from the group consisting of a cyclic mono- or poly-ester such as, diethyl cyclohexene-1,2-dicarboxylate, diethyl furane-3,4-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylate, diethyl cyclohexene-1,6-dicarboxylate, di-n-propyl 1,2-benzenediacetate, and n-butyl tetrahydrothiophene-2,3-dicarboxylate.
REFERENCES:
patent: 4442276 (1984-04-01), Kashiwa et al.
patent: 4659792 (1987-04-01), Kashiwa et al.
Kashiwa Norio
Kioka Mamoru
Toyota Akinori
Mitsui Petrochemical Industries Ltd.
Schofer Joseph L.
Teskin F. M.
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