Process for producing octadienes

Chemistry of hydrocarbon compounds – Alicyclic compound synthesis – From nonring hydrocarbon

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585368, 585367, C07C 246, C07C 1326

Patent

active

057637180

ABSTRACT:
A process for producing octadienes comprises, on synthesis of octadienes by reacting butadiene with formic acid in the presence of a palladium catalyst, controlling the reaction pressure at not more than the vapor pressure of butadiene at the reaction temperature employed, thereby suppressing formation of byproducts which would accumulate in a catalyst-containing layer and minimizing the decrease of reaction rate and selectivity which would occur by such accumulation.

REFERENCES:
patent: 4554375 (1985-11-01), Lin et al.
Musco, Journal of the Chemical Society, Perkin Transactions I, pp. 693-698 (1980) no month.

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