Process for producing N,N′-carbonyldiimidazole

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

Reexamination Certificate

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Details

C548S341500

Reexamination Certificate

active

07964626

ABSTRACT:
The present invention provides a process for producing N,N′-carbonyldiimidazole, comprising: reacting phosgene, diphosgene, or triphosgene with imidazole in an inert solvent to produce N,N′-carbonyldiimidazole; to imidazole hydrochloride yielded as a by-product in the above step, adding a gaseous or liquid basic compound represented by the below-shown general formula (1) in an inert solvent to conduct neutralization reaction; and circulating the imidazole thus generated to use it as a starting material for N,N′-carbonyldiimidazole production.In the general formula (1), R1, R2, and R3each independently represents a hydrogen atom, a methyl group, or an ethyl group. The CDI produced by the production process of the invention is a compound useful in the fields of synthesis of pharmaceutical agents, synthesis of agricultural chemicals, peptide synthesis, and the like, e.g., intermolecular condensation reactions, intramolecular condensation reactions for synthesizing N-carboxylic anhydrides, production of activated esters, and the like. The compound is especially suitable for use in applications where colorlessness is required.

REFERENCES:
patent: 6353115 (2002-03-01), Stamm et al.
patent: 6392057 (2002-05-01), Scherer et al.
patent: 8 502994 (1996-04-01), None
patent: 2002 503240 (2002-01-01), None
patent: 2002 521474 (2002-07-01), None
patent: 00 02863 (2000-01-01), None
patent: WO 00/14072 (2000-03-01), None

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