Process for producing N,N'-disubstituted paraphenylene diamine m

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C08F 4560, C08F 600, C07C 8758

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049008684

ABSTRACT:
Mixtures of N,N'-disubstituted paraphenylenediamines are produced in a process wherein a nitrogen-containing compound such as 4-nitrodiphenylamine is reductively alkylated with a plurality of ketones in sequence. Preferably, one ketone is reacted to completion with an excess of the nitrogen-containing compound, then an excess of a second ketone is added and the reaction is continued until the nitrogen-containing compound is consumed. The product is then separated from the volatiles and the unreacted portion of the second ketone is recovered.

REFERENCES:
patent: 3414616 (1968-12-01), Summers
patent: 3418373 (1968-12-01), Summers et al.
patent: 3504032 (1970-03-01), Altwicker
patent: 3542691 (1970-11-01), Budd et al.
patent: 3542692 (1970-11-01), Spacht
patent: 3929855 (1975-12-01), Summers
patent: 3933739 (1976-01-01), Wilder

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