Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...
Patent
1993-01-29
1994-09-06
McFarlane, Anthony
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
By condensation of entire molecules or entire hydrocarbyl...
585453, 585438, 585467, C07C 272
Patent
active
053448065
ABSTRACT:
There is disclosed a process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising the mixture obtained by heat treating metallic sodium together with an alkaline earth metal oxide containing a potassium compound in the atmosphere of an inert gas. According to the aforesaid process, a monoalkenyl aromatic hydrocarbon compound such as industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety from a specific aromatic hydrocarbon compound and a specific conjugated diene compound.
REFERENCES:
patent: 3244758 (1966-04-01), Eberhardt
patent: 3305599 (1967-02-01), Zadra et al.
patent: 5118895 (1992-06-01), Hibi et al.
Fushimi Norio
Inamasa Kenji
Takagawa Makoto
Achutamurthy P.
McFarlane Anthony
Mitsubishi Gas Chemical Company Inc.
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