Process for producing low polymer of α-olefin

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

Reexamination Certificate

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C585S510000, C585S901000

Reexamination Certificate

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10487728

ABSTRACT:
A process for producing an α-olefin oligomer by oligomerization of an α-olefin in a presence of a Ziegler-based catalyst, the process comprising introducing at least a portion of a reaction product which is taken out of a reactor and has a temperature of 115° C. or higher into an external heat exchanger, cooling the introduced reaction product, maintaining an oligomerization solution taken out of the external heat exchanger at a temperature of 110° C. or higher and returning at least a portion of the oligomerization solution to the reactor. In the production of an α-olefin oligomer, precipitation and adhesion of polymers at the inside of manufacturing apparatuses such as the external heat exchanger and troubles caused thereby can be prevented and a stable continuous operation can be continued for a long time.

REFERENCES:
patent: 6576721 (2003-06-01), Kobayashi et al.
patent: 6660814 (2003-12-01), Kroener et al.
patent: 3-220135 (1991-09-01), None
patent: 10-7593 (1998-01-01), None
patent: 10-7594 (1998-01-01), None
patent: 10-7595 (1998-01-01), None
patent: 10-8149 (1998-01-01), None
patent: 10-45833 (1998-02-01), None
patent: WO 00/15646 (2000-03-01), None
U.S. Appl. No. 10/257,537, filed Oct. 15, 2002, Kobayashi et al.
U.S. Appl. No. 10/489,611, filed Mar. 22, 04, Kobayashi et al.
Patent Abstracts of China, CN1184819, Jun. 17, 1998 (corresponding to US 6,660,814 B1).

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