Process for producing lithium manganese oxide suitable for use a

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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423594, 2525191, 429224, 429223, C01G 4512, H01B 106, H01M 450, H01M 432

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059852372

ABSTRACT:
A process for producing a lithium manganese oxide which has a formula of Li.sub.x MnO.sub.2 in which x is between 0.1 and 1 and which is suitable for use as a 3 volt cathode material, which comprises mixing at least one lithium compound with at least one manganese compound at a Li/Mn atomic ratio of 0.1-1 in a solvent selected from an aliphatic lower alcohol having from 1 to 3 carbon atoms, water and a mixture of the alcohol and water, allowing the resultant mixture to form a gel-like mixture, drying the gel-like mixture as required, and calcining the resulting product in an oxidative atmosphere at a temperature of 200-350.degree. C.

REFERENCES:
patent: 5496664 (1996-03-01), Sterr
patent: 5565688 (1996-10-01), Hayashi et al.
Haitao Huang and Peter G. Bruce; "3 V and 4 V lithium manganese oxide cathodes for rechargeable lithium batteries"; Journal of Power Sources; 1995; pp. 52-57.
A. Robert Armstrong and Peter G. Bruce; "Synthesis of layered LiMnO.sub.2 as an electrode for rechargeable lithium batteries"; Letters to Nature ; Jun. 6, 1996; vol. 381, pp. 499-500.
Tsutomu Ohzuku, Junji Kato, Keijiro Sawai and Taketsugu Hirai; "Electrochemistry of Manganese Dioxide in Lithium Nonaqueous Cells"; J. Electrochem. Soc.,; Sep. 1991; vol. 138, No. 9, pp. 2556-2560.

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