Process for producing light olefins using reaction with distilla

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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585638, 585639, 585310, 585324, 203 28, 203 29, 203 38, 568698, 568699, 568700, 568840, 423650, 423651, 423652, 423416, 4234182, 423437R, C07C 600, C07C 120

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058179062

ABSTRACT:
The present invention relates to a process for the production of light olefins comprising olefins having from 2 to 4 carbon atoms per molecule from a crude oxygenate feedstock. The crude oxygenate feedstock comprises an alcohol, and water. The process comprises passing the crude oxygenate feedstock to catalyst to a distillation with reaction zone to convert the alcohol to an ether and produce an ether product having a reduced water relative to the crude oxygenate feedstock and a first water stream. The ether product is passed to an oxygenate conversion zone containing a metal aluminosilicate catalyst to produce a light olefin stream. The use of crude oxygenate feedstock, having a high proportion of water, combined with a process for producing additional water in the conversion of the alcohol to an ether, actually reduces the amount of water contacted with the water sensitive, metal alumino-silicate catalyst in the oxygenate conversion zone which provides the advantage of extended catalyst life and greater catalyst stability in the oxygenate conversion zone.

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