Process for producing isobutylene and methanol

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

Reexamination Certificate

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C585S640000

Reexamination Certificate

active

06852899

ABSTRACT:
A process for producing isobutylene and methanol comprising: a first step of subjecting methyl-tert-butyl ether to decomposition in the presence of a catalyst to obtain a reaction liquid; a second step of washing the resultant with water to separate the reaction liquid into an oil layer and an aqueous layer; a third step of subjecting the oil layer to distillation to obtain a fraction containing isobutylene and a dialkyl ether from the top of a distillation column, a fraction containing methyl-tert-butyl ether and the heavy components from the bottom of the column and a fraction containing methyl-tert-butyl ether from a side cut of the column, and recycling the side cut fraction to the first step; and a fourth step of subjecting the aqueous layer to distillation to obtain a fraction containing methanol from the top of a distillation column and a fraction containing water from the bottom of the column.

REFERENCES:
patent: 4544776 (1985-10-01), Osterburg et al.
patent: 6072095 (2000-06-01), Marion et al.
patent: 6143936 (2000-11-01), Marion et al.
patent: 1165479 (1969-10-01), None
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patent: 1176620 (1970-01-01), None
patent: 1272585 (1972-05-01), None
patent: 47-41882 (1972-10-01), None
patent: 3-45053 (1991-07-01), None

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