Process for producing improved vinyl chloride polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 25P, 526 82, 326 75, 526 78, 526 86, 526219, 526232, 526227, 526266, 526318, 526343, 526345, C08F 111, C08F 334

Patent

active

039519252

ABSTRACT:
Polymer or copolymer of vinyl chloride having superior properties can be produced by suspension-polymerizing vinyl chloride or a mixture thereof with another vinyl monomer, at first, in the presence of an oil-soluble radical initiator, and thereafter, when the percentage of polymerization of the resulting polymer has reached about 15% to about 80%, subjecting the polymer to a further polymerization in the presence of a water-soluble radical initiator.
The product thus obtained has both the merits resulting from suspension polymerization and emulsion one. It has an extremely high absorptivity of plasticizer, easy processability, and film made therefrom has substantially no fish eye.

REFERENCES:
patent: 2652392 (1953-09-01), Hohenstein
patent: 3558584 (1971-01-01), Thomas
patent: 3687917 (1972-08-01), Wisseroth

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