Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing
Patent
1980-11-17
1983-02-22
Vertiz, O. R.
Chemistry of inorganic compounds
Phosphorus or compound thereof
Oxygen containing
423307, C01B 2512, C01B 2516, C01B 1516
Patent
active
043748163
ABSTRACT:
A process for producing hypophosphorous acid (H.sub.3 PO.sub.2) by reacting, in the absence of a catalyst and under an acidic condition, phosphine with an aqueous solution of hydrogen peroxide to produce an acid solution. The acid solution is then contacted with an non-transition metal hydroxide, oxide or carbonate, e.g. sodium hydroxide, to produce a product composition containing a hypophosphite, e.g. sodium hypophosphite (NaH.sub.2 PO.sub.2.H.sub.2 O). The process of this invention finds particular utility in processes of the type wherein phosphorus is reacted with an aqueous non-transition metal hydroxide composition, e.g. an aqueous suspension of a sodium hydroxide and calcium hydroxide, to produce a hypophosphite and byproduct phosphine. The process of this invention converts a substantial portion of the byproduct phosphine to hypophosphite.
REFERENCES:
patent: 2977192 (1961-03-01), Cummins
patent: 3052519 (1962-09-01), Bianchi et al.
Chemical Abstracts, vol. 76, 1972, 50585j.
Paris & Tardy, Compt. Rendu 223, 1946, 242-243.
Arzoumanidis Gregory G.
Darragh Kirk V.
Heller Gregory A.
Stauffer Chemical Company
Vertiz O. R.
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