Chemistry of inorganic compounds – Oxygen or compound thereof – Peroxide
Patent
1993-12-06
1995-03-21
Langel, Wayne
Chemistry of inorganic compounds
Oxygen or compound thereof
Peroxide
423590, C01B 15023
Patent
active
053993330
ABSTRACT:
A process for producing hydrogen peroxide by subjecting a working solution containing anthraquinones as the reaction medium, to reduction and oxidation alternately, which process is characterized in that (1) the anthraquinones as the reaction medium contained in the working solution are a mixture of an alkyl-substituted anthraquinone and an alkyl-substituted tetrahydroanthraquinone, (2) in the reduction step, the total amount of the alkyl-substituted tetrahydroanthraquinone in the working solution and part or the total amount of the alkyl-substituted anthraquinone in the working solution are reduced, and (3) in the working solution after the reduction step, the content of the alkyl-substituted anthrahydroquinone formed is kept higher than the content of the alkyl-substituted tetrahydroanthrahydroquinone formed.
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"Selectivity Aspects of the Hydrogenation Stage of the Anthraquinone Process for Hydrogen Peroxide Production", Berglin et al., 1982 American Chemical Society, pp. 150-153.
Ishiuchi Yukio
Kato Tomio
Minato Kazuyuki
Ogasawara Kazuharu
Takamiya Hiroshi
Langel Wayne
Mitsubishi Chemical Gas Co., Ltd.
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