Chemistry of inorganic compounds – Hydrogen or compound thereof – Elemental hydrogen
Reexamination Certificate
2005-08-09
2005-08-09
Silverman, Stanley S. (Department: 1754)
Chemistry of inorganic compounds
Hydrogen or compound thereof
Elemental hydrogen
C252S373000
Reexamination Certificate
active
06926881
ABSTRACT:
There is disclosed a process for producing a hydrogen-containing gas, which comprises reacting methanol, steam and oxygen in the presence of (1) a catalyst comprising platinum and zinc oxide, wherein the content of the platinum is in the range of 5 to 50% by weight based on the total amount of the platinum and zinc oxide, or (2) a catalyst comprising platinum, zinc oxide and chromium oxide, wherein the atomic ratio of zinc to chromium (zinc/chromium) is in the range of 2 to 30, or (3) a catalyst comprising platinum, zinc oxide and at least one element selected from the group consisting of lead, bismuth and indium. Each of the catalysts has a high activity and is excellent in heat resistance and selectivity to steam-reforming reaction, and accordingly is capable of efficiently producing a reformed gas which is composed principally of hydrogen and is well suited for use in a fuel cell and the like by means of auto thermal reaction reaction, while lowering the concentration of carbon monoxide in a reformed hydrogen-containing gas.
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N. Iwasa, et al., “New catalytic functions of Pd-Zn, Pd-Ga, Pd-In, Pt-Zn, Pt-Ga and Pt-In alloys in the conversions of methanol”, Catalysis Letters, vol. 54, No. 3, pp. 119-123, 1998.
Hiramatsu Yasushi
Hirose Shigeyuki
Ikoma Futoshi
Katagiri Masayuki
Takamura Koki
Antonelli Terry Stout & Kraus LLP
Medina Maribel
Mitsubishi Gas Chemical Company Inc.
Silverman Stanley S.
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