Process for producing homoallyl alcohols

Details Process for producing homoallyl alcohols Process for producing homoallyl alcohols

1989-10-16

1991-02-05

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568857, 568698, C07L 2960

Patent

active

049906976

ABSTRACT:
A process for producing homoallyl alcohols of the general formula (I) ##STR1## in which either A.sup.1 or A.sup.3 represents a hydrogen atom, the other represents a single bonding along with A.sup.2 ; R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and independently represents a hydrogen atom, or an alkyl or alkenyl group with or without being substituted with a hydroxyl group or an akoxyl group; and Y represents a hydrogen atom, an alkyl group or an alkenyl group, by reacting 1,3-glycols of the general formula (II) ##STR2## in which X and Y are the same or different and independently represents a hydrogen atom, an alkyl group or an alkenyl group, R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 independently represents as defined above, at a temperature in the range of 130.degree. to 250.degree. C. in liquid phase with the contact of .gamma.-alumina catalyst.

REFERENCES:
patent: 3966829 (1976-06-01), Engelhardt et al.

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