Process for producing high trans low vinyl conjugated diene (co)

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

526173, 526335, 526340, C08F 452

Patent

active

050861360

ABSTRACT:
A process for producing a high trans low vinyl conjugated diene (co)polymer, comprising polymerizing at least one conjugated diene alone or in combination with at least one alkenyl compound using a catalyst composition comprising (a) a barium compound, (b) an organoaluminum compound, (c) an organolithium compound and (d) a hydroxyl group-containing organic compound. This process enables the easy production of a high trans low vinyl conjugated diene (co)polymer having a high trans 1,4 bond content, a low vinyl bond content and a high molecular weight, at a high polymerization activity.

REFERENCES:
patent: 4080492 (1978-03-01), deZarauz et al.
patent: 4129705 (1978-12-01), de Zarauz
patent: 4424322 (1984-01-01), Hattori et al.
patent: 4933401 (1990-04-01), Hattori et al.
Polymer Sci., USSR, 18, 1976, pp. 2325-2330, Z. M. Baidakova et al., "Butadiene Polymerization in the Presence of Initiators of the Type Barium Alcoholates-Organomagnesium Compound".
Macromol. Chem., 156, 1972, pp. 31-38, P. Maleki, et al., "Etude du Mecanisme Des Polymizarisations Amorcees Par Les Metaux Alcalino-Terreux".
Journal of the Chemical Society of Japan (Pure Chemistry Section), 1972, No. 2, pp. 447-453, R. Fujio, et al., "COPOLYMERIZATION OF BUTADIENE AND STYRENE WITH N-BUTYLLITHIUM AND ALKALINE-EARTH METAL COUMPOUND MITURE".
Journal of the Chemical Society of Japan (Industrial Chemistry Section), 72, pp. 994-998, (with partial English translation), T. Narita, et al., "COPOLYMERIZATION REACTION OF STYRENE, BUTYLLITHIUM-POLYETHER SYSTEM CATALYST".
J. Macromol. Sci. Chem. A4(4), pp. 885-896, Jul. 1970, T. Marita, et al., "REACTRIVITY OF N-BUTYLLITHIUM-(CH.sub.3).sub.2 NCH.sub.2 CH.sub.2 OLI SYSTEM AS CATALYST FOR COPOLYMERIZATION OF STYRENE WITH 1,3-BUTADIENE".
Journal of the Chemical Society of Japan (Pure Chemistry Section), pp. 440-446, 1972, (with English Abstract), R. Fujio, et al., "HOMOPOLYMERIZATION OF BUTADIENNE AND ISOPRENE AND COPOLYMERIZATION OF BUTADIENE WITH STYRENE BY USING ORGANOALKALINE-EARTH . . . ".

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for producing high trans low vinyl conjugated diene (co) does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for producing high trans low vinyl conjugated diene (co), we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for producing high trans low vinyl conjugated diene (co) will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-348639

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.