Process for producing high tenacity and high modulus polyethylen

Plastic and nonmetallic article shaping or treating: processes – Forming continuous or indefinite length work – Shaping by extrusion

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2642107, 2642108, D01F 604, D02J 122

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053425677

ABSTRACT:
A process for producing high tenacity and high modulus polyethylene fiber gel spinning. Cycloalkane and cycloalkene are selected as solvents for dissolving ultra-high molecular weight polyethylene, and a volatile solvent such as cyclohexanone or a mixture thereof is selected as an extracting solvent. The present process allows the extracted fibers to be stretched directly after the spinning step without requiring an intermediate winding step. The resulting fibers from the present invention have a tenacity greater than 15 g/d, a modulus greater than 350 g/d, an elongation at break less than 10%, and a crystallinity greater than 60%.

REFERENCES:
patent: 3048465 (1962-08-01), Jurgeleit
patent: 3962205 (1976-06-01), Ward
patent: 4020266 (1977-04-01), Frank
patent: 4137394 (1979-01-01), Meihuizen
patent: 4344908 (1982-08-01), Smith
patent: 5286435 (1994-02-01), Slutsker et al.
The Properties of Polyethylene Crystallized Under the Orientation and Pressure Effects of a Pressure Capillary Viscometer (1990 by John Wiley & Sons, Inc.) (Journal of Applied Polymer Science vol. 14, pp. 2305-2317 (1970)) Southern et al.
On Ultra-High Tensile by Drawing Single Crystal Mats of High Molecular Weight Polyethylene (Polymer Journal. vol. 15, No. 4, pp. 327-329 (1983)) Kanamoto.

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