Process for producing high RON gasoline using CFI Zeolite

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

Reexamination Certificate

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C208S111350, C585S734000, C585S737000, C585S752000, C585S820000

Reexamination Certificate

active

07037422

ABSTRACT:
A process for producing a high RON naphtha which comprises contacting a hydrocarbon feed stream comprising a mixture of the isomers of C5and C6paraffins with a CFI zeolite, such as CIT-5, in an adsorption zone, whereby the branched isomers of the C5and C6paraffins are preferentially adsorbed by the CFI zeolite as compared to the straight chain isomers, and recovering a naphtha product from the adsorption zone having a higher RON than the hydrocarbon feed stream, also including a hydroisomerization process and a hydrocracking process.

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G.G. Podrebarac, et al., “More Uses for Catalytic Distillation” in Chemtech, May 1997, pp. 37-45, 0009-2703/97 1997 American Chemical Society.
D.S. Santilli et al., “Inverse Shape Selectivity in Molecular Sieves: Obervations, Modelling, and Predictions”, Microporous Materials, 1 (1993), pp. 329-341, Elsevier Science Publishers B.V., AMSTERDAM, 0927-6513/93—Elsevier Science Publishers B.V.
Merijn Schenk et al., “Understanding Zeolite Catalysis: Inverse Shape Selectivity Revised”, Angew. Chem. Int. Ed. 2002, 41. No. 14, pp. 2499-2502.

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