Process for producing furnace atmospheres using noncryogenically

Chemistry of inorganic compounds – Nitrogen or compound thereof

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148230, 148238, C01B 2104

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active

053226763

ABSTRACT:
A process for producing low-cost furnace atmospheres suitable for annealing and heat treating ferrous and nonferrous metals and alloys, brazing metals and ceramics, sealing glass to metal, and sintering metal and ceramic powders in a continuous furnace equipped with an ammonia dissociator from non-cryogenically produced nitrogen containing from 0.05 to 5.0% residual oxygen is presented. The disclosed process involves mixing non-cryogenically produced nitrogen with a pre-determined amount of a reducing gas such as hydrogen, ammonia, a C, H, and O containing hydrocarbon such as an alcohol, an ether, etc., or a mixture thereof, passing the mixture through an ammonia dissociator and converting the residual oxygen to an acceptable form such as moisture, carbon monoxide, carbon dioxide, or mixture thereof, and using the resultant gaseous mixture for annealing and heat treating ferrous and nonferrous metals and alloys, brazing metals and ceramics, sealing glass to metal, and sintering metal and ceramic powders.

REFERENCES:
patent: 3379507 (1968-04-01), Becker et al.
patent: 3598538 (1971-08-01), Peacock
patent: 4179407 (1979-12-01), Iiyama
patent: 4605579 (1990-10-01), Campbell
patent: 4704267 (1987-11-01), Dimartino
P. Murzyn & L. Flores, Jr., Carburizing with Membrane N.sub.2 : process and quality issues, Mar. 1988, pp. 28-32.
H. Walton, New Method of Generating Nitrogen for Controlled Atmosphere Heat Treatment at Torrington Shiloh Plant, Mar. 1986 pp. 40-46.
P. F. Stratton, The Use of Non-Cryogenically Produced Nitrogen in Furnace Atmospheres, 1989, pp. 63-67.
D. J. Bowe & D. L. Fung, How PSA Nitrogen Works in a Heat Treating Shop, pp. 30-33, no date.

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