Compositions – Gaseous compositions – Nitrogen and hydrogen containing
Patent
1992-12-22
1994-03-01
Langel, Wayne
Compositions
Gaseous compositions
Nitrogen and hydrogen containing
148230, 148238, 252374, 423351, C06D 700
Patent
active
052904806
ABSTRACT:
A process for producing low-cost furnace atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering non-ferrous metal and ceramic powders from non-cryogenically produced nitrogen containing from 0.05 to 5.0% residual oxygen is presented. The disclosed process involves 1) mixing non-cryogenically produced nitrogen with a predetermined amount of dissociated ammonia, 2) passing the mixture through a low-pressure drop catalytic reactor, 3) converting the residual oxygen to an acceptable form such as moisture and reducing the residual oxygen level to below about 10 ppm, and 4) using the resultant gaseous mixture for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering non-ferrous metal and ceramic powders. The key feature of the disclosed process involves the use of a novel low-pressure drop catalytic reactor for converting residual oxygen with dissociated ammonia to moisture.
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P. F. Strutton, The Use of Non-Cryogenically Produced Nitrogen in Furnace Atmospheres, 1989, pp. 63-67.
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Bonner Brian B.
Eichelberger Donald P.
Garg Diwakar
Kilhefner Paul T.
Air Products and Chemicals Inc.
Langel Wayne
Marsh William F.
Simmons James C.
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