Process for producing fluoropolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S242000, C526S247000, C526S249000, C526S250000, C526S253000, C526S254000, C526S255000, C526S348800, C562S008000, C562S025000

Reexamination Certificate

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07989566

ABSTRACT:
An emulsion polymerization process for the production of non-elastomeric fluoropolymers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X-Rf-(CH2)n—O—P(O)(OM)2, wherein n is 1 or 2, X═H or F, M=a univalent cation, and Rf is a C4-C6fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.

REFERENCES:
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patent: 2559752 (1951-07-01), Berry
patent: 2597702 (1952-05-01), Benning
patent: 4262101 (1981-04-01), Hartwimmer et al.
patent: 4380618 (1983-04-01), Khan et al.
patent: 5738802 (1998-04-01), Yamamoto et al.
patent: 5789508 (1998-08-01), Baker et al.
patent: 6395848 (2002-05-01), Morgan et al.
patent: 2006/0229398 (2006-10-01), Urban
patent: 2004-358397 (2004-12-01), None

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