Process for producing fluorocarboxylic anhydride

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid anhydrides

Reexamination Certificate

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Reexamination Certificate

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06903236

ABSTRACT:
A method of producing (RfCO)2O by reacting RfCOCl with MmCO3can efficiently synthesize a fluorocarboxylic anhydride in a one-step reaction,wherein Rfis a saturated hydrocarbon group having 1 to 20 carbon atoms, which optionally has an oxygen atom, in which all or part of hydrogen atoms are substituted with a fluorine atom, or a fluorine atom and another halogen atom, M is an alkali metal or an alkali earth metal, m is 2 when M is the alkali metal, or 1 when M is the alkali earth metal.

REFERENCES:
patent: 3676491 (1972-07-01), Wada et al.
patent: 4595541 (1986-06-01), Amiet et al.
patent: 45-38523 (1970-12-01), None
patent: 45 38523 (1970-12-01), None
patent: 46 6888 (1971-02-01), None
patent: 61 33139 (1986-02-01), None
Bourne et al., J. Chem. Soc. (1949) 2976-2979.

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