Process for producing ethanol from corn dry milling

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing oxygen-containing organic compound

Reexamination Certificate

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C435S161000, C435S162000

Reexamination Certificate

active

07074603

ABSTRACT:
A process for producing ethanol by the conversion of carbohydrates from a corn dry milling process in which the bottoms fraction from distillation of ethanol in a conventional yeast fermentation is used in a process including a combination of biochemical and synthetic conversions. The process results in high yield ethanol production with concurrent production of high value coproducts. An acetic acid intermediate is produced from bottoms fraction, followed by conversion of the acetic acid into ethanol using esterification and hydrogenation reactions. Coproducts of the process include a high protein content solids fraction produced in the fermentation.

REFERENCES:
patent: 3956482 (1976-05-01), Hahn et al.
patent: 4140799 (1979-02-01), Nagodawithana et al.
patent: 4282323 (1981-08-01), Yates
patent: 4359404 (1982-11-01), Grey et al.
patent: 4405717 (1983-09-01), Urbas
patent: 4421939 (1983-12-01), Kiff et al.
patent: 4497967 (1985-02-01), Wan
patent: 4506012 (1985-03-01), Reed
patent: 4517391 (1985-05-01), Schuster et al.
patent: 4568644 (1986-02-01), Wang et al.
patent: 4652526 (1987-03-01), Hsu
patent: 4771001 (1988-09-01), Bailey et al.
patent: 5071754 (1991-12-01), Walkup et al.
patent: 5308619 (1994-05-01), Schneider et al.
patent: 5599976 (1997-02-01), Scates et al.
patent: 5753474 (1998-05-01), Ramey
patent: 5892102 (1999-04-01), Mikami et al.
patent: 6509180 (2003-01-01), Verser et al.
patent: 6703227 (2004-03-01), Jakel et al.
patent: 6740508 (2004-05-01), Ulrich et al.
patent: WO 83/03409 (1983-10-01), None
Agreda et al., Chem. Eng. Prog., “High Purity Methyl Acetate by Reactive Distillation”, pp. 40-46, Feb. 1990.
Balasubramanian, N., Kim, J.S., Lee, Y.Y., “Fermentation of Xylose into Acetic Acid byClostridium thermoaceticum”,Appl Biochem and Biotech, vol. 91-93, p. 367-376, 2001.
Bock, S.A., Fox, S.L., Gibbons. W.R., “Development of a Low-Cost, Industrially Suitable Medium for the Production of Acetic Acid fromClostridium thermoaceticum”,Biotechnology and Applied Biochemistry, vol. 25, p. 117-125, 1997.
Borden, J.R., Lee, Y.Y., Yoon, H.H., “Simultaneous Saccharification and Fermentation of Cellulosic Biomass to Acetic Acid”, Appl Biochem and Biotech, vol. 84-86, p. 963-970, 2000.
Brownell, J., Nakas, J., “Bioconversion of Acid-Hydrolyzed Poplar Hemicellulose to Acetic Acid byClostridium thermoaceticum”,J. Ind. Microbiol, vol. 7, p. 1-6, 1991.
Busche et al., Biotechnol. Bioeng. Symp., “Recovery of Acetic Acid From Dilute Acetate Solution”, No. 12, pp. 249-262 (1982).
Chang, V.S., Holtzapple, M.T., “Fundamental Factors Affecting Biomass Enzymatic Reactivity”, Appl. Biochem. and Biotech., vol. 84-86, p. 5-37, 2000.
Daniel, S.L., Keith, E.S., Yang, H., Lin, Y.S., Drake, H.L., “Utilization of Methoxylated Aromatic Compounds by the AcetogenClostridium thermoaceticum:Expression and Specificity of the CO-Dependent O-Demethylating Activity”, Biochemical and Biophysical Research Communications, vol. 180, No. 1, p. 416-422, Oct. 15, 1991.
Grohmann et al., Process Biochem., “Saccharification of Corn Fibre by Combined Treatment With Dilute Sulphuric Acid and Enzymes”, vol. 32, No. 5, pp. 405-415 (1997).
Hull, S.R., Yang, B.Y., Venzke, D., Kulhavy, K., Montgomery, R., “Composition of Corn Steep Water During Steeping”, J. Agric. Food Chem., vol. 44, p. 1857-1863, 1996.
Luedeking et al., J. Biochem. Microbiol. Tech. Eng., “A Kinetic Study of the Lactic Acid Fermentation; Batch Process at Controlled PH”, Robert Luedeking & Edgar L. Piret, vol. 1, No. 1, pp. 393-412, 1959.
Lundie (Jr.), L.L., Drake, H.L, “Development of a Minimally Defined Medium for the AcetogenClostridium thermoaceticum”,J. of Bacteriology, vol. 159, No. 2, p. 700-703, 1984.
Savage, M.D., Drake, H.L., “Adaptation of the AcetogenClostridium thermoautotropicumto Minimal Medium”, Journal of Bacteriology, vol. 165, No. 1, p. 315-318, 1986.
Tang et al., Appl. Microbiol. Biotechnol., “Acetic Acid Production From Whey Lactose by the Co-Culture ofStrepococcus lactisandClostridium formicoaceticum”,28:138-143 (1988).
Wang et al., Biochem. Eng. Renewable Sources, “A Novel Route to the Production of Acetic Acid by Fermentation”, No. 181, vol. 74, pp. 105-110 (1978).
Witjitra, K., Shah, M.M., Cheryan, M., “Effect of Nutrient Sources on Growth and Acetate Production byClostridium thermoaceticum”,Enzyme and Microbial Technology, vol. 19, p. 322-327, 1996.
Xu et al., Canadian J. Chem. Eng., “Kinetics of Acetic Acid Esterification Over Ion Exchange Catalysts”, vol. 74, pp. 493-500, Aug. 1996.
Yang et al., Biotechnol. Bioeng., “Kinetics and Mathematical Modeling of Homoacetic Fermentation of Lactate byClostridium formicoaceticum”,vol. 32, pp. 797-802 (1988).

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