Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1981-11-03
1982-09-14
Torrence, Dolph H.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
71105, C07C12175
Patent
active
043494889
ABSTRACT:
2,6-dibromo-4-cyanophenyl octanoates and other esters of 3,5-dibromo-4-hydroxybenzonitrile may be produced by reacting 4-hydroxybenzonitrile with bromine in the presence of an inert solvent and catalytic amounts of a basic heterocyclic aromatic compound or its hydrohalide, followed by removal of unreacted bromine and addition of octanoyl chloride or other acyl halide to the reaction mixture and recovery of the desired ester together with recyclable pyridine hydrohalide catalyst and solvent.
REFERENCES:
patent: 3349111 (1967-10-01), Luckenbaugh
patent: 3397054 (1968-08-01), Hart et al.
patent: 3592626 (1971-07-01), Heywood et al.
patent: 3671556 (1972-06-01), Goldstick
Auwers and Reis (1896) reported In Cook, et al., "Biological Activity Of Various Halogenated Derivatives of Ioxynil," Northwest Weed Control Conf., vol. 19, pp. 321-323 (1965).
E. Muller, et al., Chem. Ber. 92 2278 (1959).
Carpenter et al., "Chemical and Biological Properties of Two New Herbicides-Ioxynil and Bromoxynil", Weed Res. (1964) 4 175-195.
Dentel David A.
Sanders David C.
Great Lakes Chemical Corporation
Torrence Dolph H.
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