Process for producing dimethyl ether form synthesis gas

Details Process for producing dimethyl ether form synthesis gas Process for producing dimethyl ether form synthesis gas

1984-03-22

1985-06-04

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Group viii metal containing catalyst utilized for the...

Group ia or iia light metal containing material utilized...

502161, C07C 2706

Patent

active

045215405

ABSTRACT:
This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

REFERENCES:
patent: 3894102 (1975-07-01), Chang et al.
patent: 3941819 (1976-03-01), Vannice et al.
patent: 4098809 (1978-07-01), Pagnal
patent: 4154751 (1979-05-01), McVicker et al.
patent: 4177167 (1979-12-01), Manara et al.
patent: 4328129 (1982-05-01), Huang
React. Kinet. Catal. Lett., vol. 20, Nos. 1-2, 175-180(1982), Light Olefin Production from CO/H.sub.2 Over Silica Supported Fe/Mn/K Catalysts Derived From a Bimetallic Carbonyl Anion, [Fe.sub.2 Mn (CO).sub.12 ].

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