Process for producing Diels-Alder adducts while inhibiting the f

Chemistry of hydrocarbon compounds – Alicyclic compound synthesis – Polycyclic product

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585950, 526 83, 526 84, C07C 300

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active

045380139

ABSTRACT:
A process for preventing the formation of polymeric by-products during the production of Diels-Alder adducts is improved by the addition of NO or of a compound splitting off NO in situ, as a polymerization inhibitor. This process is especially effective for preventing the formation of polymeric by-products in the manufacture of 5-vinylnorbornene-2. In a tubular reactor, when observing narrow temperature and pressure ranges, a high selectivity is obtained in the production of this adduct.

REFERENCES:
patent: 2752403 (1956-06-01), Schutze et al.
patent: 4079091 (1978-03-01), Matsuno
Chemical Abstract 84: 150176k, (Kisaki et al.).
Chemical Abstract 85: 63629n, (Watson).
Chemical Abstract 86: 44221c, (Watson).
Chemical Abstract 89: 44276m, (Li et al.).

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