Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Reexamination Certificate
2009-01-13
2011-12-27
Witherspoon, Sikarl (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C568S631000, C568S798000, C585S467000
Reexamination Certificate
active
08084648
ABSTRACT:
In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
REFERENCES:
patent: 3412165 (1968-11-01), Slaugh et al.
patent: 3536771 (1970-10-01), Graff
patent: 3760018 (1973-09-01), Suggitt et al.
patent: 3760019 (1973-09-01), Crone, Jr. et al.
patent: 3784618 (1974-01-01), Suggitt et al.
patent: 3839477 (1974-10-01), Suggitt et al.
patent: 3957687 (1976-05-01), Arkell et al.
patent: 3962362 (1976-06-01), Suggitt
patent: 4021490 (1977-05-01), Hudson
patent: 4094918 (1978-06-01), Murtha et al.
patent: 4122125 (1978-10-01), Murtha et al.
patent: 4152362 (1979-05-01), Murtha
patent: 4177165 (1979-12-01), Murtha et al.
patent: 4206082 (1980-06-01), Murtha et al.
patent: 4219689 (1980-08-01), Murtha
patent: 4268699 (1981-05-01), Murtha et al.
patent: 4329531 (1982-05-01), Murtha et al.
patent: 4439409 (1984-03-01), Puppe et al.
patent: 4447554 (1984-05-01), Murtha et al.
patent: 4826667 (1989-05-01), Zones et al.
patent: 4954325 (1990-09-01), Rubin et al.
patent: 5236575 (1993-08-01), Bennett et al.
patent: 5250277 (1993-10-01), Kresge et al.
patent: 5334795 (1994-08-01), Chu et al.
patent: 5362697 (1994-11-01), Fung et al.
patent: 5557024 (1996-09-01), Cheng et al.
patent: 6077498 (2000-06-01), Diaz Cabanas et al.
patent: 6489529 (2002-12-01), Cheng et al.
patent: 6506953 (2003-01-01), Cheng et al.
patent: 6730625 (2004-05-01), Chang et al.
patent: 6936744 (2005-08-01), Cheng et al.
patent: 2004/0092757 (2004-05-01), Oguchi et al.
patent: 2005/0158238 (2005-07-01), Tatsumi et al.
patent: 2008/0027256 (2008-01-01), Roth et al.
patent: 2008/0027259 (2008-01-01), Roth et al.
patent: 2008/0045768 (2008-02-01), Roth et al.
patent: 2011/0037022 (2011-02-01), Dakka et al.
patent: 0 293 032 (1988-11-01), None
patent: 0 338 734 (1989-10-01), None
patent: 95/31421 (1995-11-01), None
patent: 97/17290 (1997-05-01), None
patent: 01/53236 (2001-07-01), None
patent: 01/74767 (2001-10-01), None
patent: 2005/118476 (2005-12-01), None
patent: 2009/038900 (2009-03-01), None
I. Borodina et al., “Hydroalkylation of Benzene and Ethylbenzene over Metal Containing Zeolite Catalysts”, Microporous and Mesoporous Materials, 2007, vol. 105, pp. 181-188.
W. Fan et al., “Synthesis and Catalytic Properties of a New Titanosilicate Molecular Sieve with the Structure Analogous to MWW-type Lamellar Precursor”, Journal of Catalyst, 2006, vol. 243, pp. 183-191.
S. Kim et al., “Structural Evolution of B-MCM-36 and B-ITQ-2 from B-MCM-22”, Bull. Korean Chem. Society, 2006, vol. 27, No. 10, pp. 1693-1696.
S. Lawton et al., “Zeolite MCM-49: A Three-Dimensional MCM-22 Analogue Synthesized by in Situ Crystallization”, Journal of Physical Chemistry, 1996, vol. 100, pp. 3788-3798.
S. Maheshwari et al., “Layer Structure Preservation During Swelling, Pillaring, and Exfoliation of a Zeolite Precursor”, Journal of American Chemical Soc., 2008, vol. 130, pp. 1507-1516.
J. Ruan et al., “Structure Elucidation of the Highly Active Titanosilicate Catalyst Ti-YNU-1”, Angew. Chem. Int. Ed., 2005, vol. 44, pp. 6719-6723.
L. Slaugh et al., “Hydrodimerization of Benzene to Phenylcyclohexane over Supported Transition Metal Catalysts”, Journal of Catalysis, 1969, vol. 13, pp. 385-396.
P. Wu et al., “Methodology for Synthesizing Crystalline Metallosilicates with Expanded Pore Windows Through Molecular Alkoxysilylation of Zeolitic Lamellar Precursors”, Journal of American Chemical Soc., 2008, vol. 130, pp. 8178-8187.
L. Zhicheng et al., “Static Synthesis of High-Quality MCM-22 Zeolite with High SiO2/Al2O3Ratio”, Chinese Science Bull, 2004, vol. 49, No. 6, pp. 556-561.
Buchanan John S.
Chen Tan-Jen
Cheng Jane C.
Lattner James R.
ExxonMobil Chemical Patents Inc.
Sullivan Jamie L.
Witherspoon Sikarl
LandOfFree
Process for producing cyclohexylbenzene does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for producing cyclohexylbenzene, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for producing cyclohexylbenzene will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-4309414