Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – Diolefin product
Patent
1980-12-18
1982-07-06
Douglas, Winston A.
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
Diolefin product
585610, 585639, C07C 124
Patent
active
043384781
ABSTRACT:
A process for producing a conjugated diene represented by the general formula ##STR1## wherein R.sub.3, R.sub.4 and R.sub.5 each represent a hydrogen atom, or any one of them represents a methyl group and the other two each represent a hydrogen atom,
which comprises heating an alkane-1,3-diol represented by the general formula ##STR2## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom, or one of them represents a hydrogen atom and the other represents a methyl group,
to a temperature of at least 130.degree. C. in the liquid phase in the presence of water and a boron-oxyacid or an oxygen-containing boron compound capable of forming a boron-oxyacid it under the reaction conditions.
REFERENCES:
patent: 1179408 (1916-04-01), Delbruck et al.
patent: 3890404 (1975-06-01), Takagi et al.
Chemical Abstracts; vol. 63; 8176f (1965).
Hino Ken-ichi
Kyo Sunao
Omura Katsumi
Douglas Winston A.
Howard Jacqueline V.
Kuraray Co. Ltd.
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