Process for producing cis-jasmone

Details Process for producing cis-jasmone Process for producing cis-jasmone

1976-01-15

1977-08-30

Morgenstern, Norman

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252522, C07C 4500

Patent

active

040454894

ABSTRACT:
A process is described for the preparation of cis-jasmone according to the reaction: ##STR1## wherein X is chloro or bromo and wherein M is alkali metal, the reaction being carried out (1) using a "phase transfer agent" and (2) in a two phase system.

REFERENCES:
patent: 3668255 (1972-06-01), Meuly
patent: 3983175 (1976-09-01), Tamai et al.
Tsukasa et al, "Chemical Abstracts", 135501g (1974), cited by applicants.
"Eastman Org. Chemical Bulletin", vol. 48, No. 1, pp. 1-3 (1976).
Jonczyk et al., "Tetrahedron Lett", p. 1351 (1971).
Brandstrom et al., "Tetrahedron Lett", p. 473, (1972).

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