Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1977-05-11
1978-08-15
Thomas, Jr., James O.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C 2900
Patent
active
041072197
ABSTRACT:
A chain terpene alcohol having the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and respectively represent hydrogen atom or a lower alkyl group is produced by oxidizing a chain unsaturated amine having the formula ##STR2## wherein R.sup.3 represents an alkyl group and heating the product for a thermal rearrangement to form a chain unsaturated hydroxylamine having the formula ##STR3## and then reducing the chain unsaturated hydroxylamine with hydrogen in the presence of a catalyst selected from the group consisting of iron family elements, copper family elements, oxides thereof and copper chromite.
REFERENCES:
takabe et al., Chem. Abst., vol. 83, p. 411, #206433r (1975).
Cope et al., J.A.C.S., vol. 71, pp. 3423-3428 (1949).
Routenstrauch, Helv. Chim. Acta. vol. 56, pp. 2492-2508 (1973).
Takabe et al., Tetrahedron Litt, #34, pp. 3005-3006 (1975).
Fieser et al., Reagents for Organic Synthesis, pp. 723-730 (1964).
Ikeda Hisao
Murata Atsuo
Suzuki Hideo
Tsuchiya Shuji
Nissan Chemical Industries Ltd.
Reamer James H.
Thomas, Jr. James O.
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