Process for producing catalyst body for production of...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

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C502S527130, C502S524000, C502S300000

Reexamination Certificate

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08034738

ABSTRACT:
It is intended to highly efficiently produce a high-density brush-shaped carbon nanostructure useful in the production of CNT assembly, such as rope-shaped CNTs, and provide a catalyst body for production of brush-shaped carbon nanostructure that enables the production. The catalyst body for production of brush-shaped carbon nanostructure is one comprising a substrate (32), an aggregation suppressive layer (34) superimposed on a surface thereof and a catalyst layer superimposed on the aggregation suppressive layer (34). The catalyst layer is a catalyst particle layer (44) consisting of metallic catalyst particles (42) composed mainly of a catalytic metal. The metallic catalyst particles (42) have an average particle diameter, D, satisfying the relationship 0.5 nm≦D≦80 nm, and individual particles of the metallic catalyst particles (42) have a diameter, d, falling within the range of the above average particle diameter (D). Further, there are disclosed a process for producing the catalyst body, a brush-shaped carbon nanostructure and a process for producing the same.

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K. Bartsch et al., “Effects of catalyst pre-treatment on the growth of single-walled carbon . . . ”, Science Direct, Dec. 5, 2006, pp. 543-552, vol. 45, Elscvier Ltd.
Baratunde A. Cola et al., “Photoacoustic characterization of carbon nanotube . . . ”, The Journal of Applied Physics, Mar. 12, 2007, pp. 054313-1 to 054313-9, vol. 101.
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Kenji Nishimura et al., “In situ study of iron catalysts for carbon nanotube growth . . . ”, The Japanese Journal of Applied Physics, 2004, pp. L471-L474, vol. 43, No. 4A.

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