Process for producing carbon monoxide and hydrogen from methanol

Chemistry of inorganic compounds – Carbon or compound thereof – Oxygen containing

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423648R, 252373, C01B 3118, C01B 113

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active

043168809

ABSTRACT:
A process is described for producing carbon monoxide and hydrogen which comprises contacting methanol vapor at a temperature of 200.degree. to 500.degree. C. with an indirectly heated zinc containing catalyst while said methanol vapor is at a pressure in a range of 2 to 50 bars, whereby to obtain an effluent gas in which the components of carbon monoxide and hydrogen constitute at least 90% by volume of said gas, removing at least a part of the impurities from said effluent gas and separating said effluent gas into its carbon monoxide and hydrogen components by adsorption. The effluent gas can be separated into its carbon monoxide and hydrogen components by use of a plurality of adsorbers containing zeolite-type molecular sieve material where the zeolite is substantially permeable to hydrogen but sorbs carbon monoxide.

REFERENCES:
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patent: 4091086 (1978-05-01), Hinden et al.
patent: 4129424 (1978-12-01), Armand
patent: 4175115 (1979-11-01), Ball et al.
Morelli, et al, "Journ. of Cat." 26 (1972) pp. 106-111.

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