Process for producing carbon fabric

Chemistry of inorganic compounds – Carbon or compound thereof – Elemental carbon

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264 292, 4234474, 4234476, D01F 922

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active

042371090

ABSTRACT:
Provided is a process for producing a carbon fabric composed of carbon fibers having improved tensile strength and modulus of elasticity from a precursor fabric made of an acrylonitrile polymer fiber. The acrylonitrile polymer fiber used has a fusing temperature of at least 310.degree. C., contains not more than 0.1 wt. % of a residual solvent, and is prepared by a process wherein an acrylonitrile polymer comprised of at least 94 wt. % of acrylonitrile and not more than 6 wt. % of another comonomer and having an intrinsic viscosity of 1.4-2.3 is spun into filaments and then the filaments are stretched at a total stretching ratio of at least 6. The fiber of the fabric woven therefrom is treated with a transition metal-containing compound. The precursor fabric exhibits a free areal shrinkage of not more than 50% and has a weight per unit area falling within the specified range. The precursor fabric is heated in an oxidizing gas atmosphere at 200.degree.-400.degree. C. under conditions such that the fabric is permitted to shrink by at least 80% of the free areal shrinkage, and then, carbonized at at least 700.degree. C. in a non-oxidizing atmosphere.

REFERENCES:
patent: 3285696 (1966-11-01), Tsunoda
patent: 3497318 (1970-02-01), Noss
patent: 4069297 (1978-01-01), Saito et al.

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