Process for producing bromomethylated polyphenylene ethers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525391, 525392, 525395, 525396, 525397, 525905, C08L 7104, C08G 6548

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045593922

ABSTRACT:
Polyphenylene ethers, especially poly(2,6-dimethyl-1,4-phenylene) ether, are reacted, in the presence of carboxylic acids, with formaldehyde and hydrogen bromide, whereby 0.02-1 bromomethyl group is introduced, per phenyl nucleus, and a product is obtained containing up to 37.6% by weight of bromine, and losing 2-40% of its weight by thermogravimetric analysis at 250.degree.-325.degree. C. The resultant bromomethylated polyphenylene ethers are suitable, inter alia, as flame retardants.

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