Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1998-08-25
1999-03-09
Barts, Samuel
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C07C 5116
Patent
active
058803130
ABSTRACT:
A process for continuously producing an aromatic carboxylic acid comprising oxidizing an aromatic compound substituted with alkyl groups with molecular oxygen gas in the liquid phase in a solvent containing a lower aliphatic carboxylic acid in the presence of a catalyst comprising heavy metal compounds and a bromine compound, wherein a mother liquor which is obtained after removal of crystals from a reaction liquid of the liquid phase oxidation and contains heavy metal ions and bromine ion as catalyst components is brought into contact with a chelate resin of an anion exchange type to recover the catalyst components.
The catalyst components are efficiently recovered, and auxiliary agents in an amount exceeding the equivalent amount and excessive labor are not necessary.
REFERENCES:
patent: 4162991 (1979-07-01), Jones
patent: 4317919 (1982-03-01), Jones et al.
patent: 5731466 (1998-03-01), Kida
Fujita Hideaki
Inari Masato
Matsumoto Masami
Zaima Fumiya
Barts Samuel
Mitsubishi Gas Chemical Company Inc.
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