Process for producing aqueous solution of calcium nitrite

Chemistry of inorganic compounds – Nitrogen or compound thereof – Oxygen containing

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423235, C01B 2120

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042737540

ABSTRACT:
An aqueous solution of calcium nitrite having high purity and high concentration is obtained by contacting a nitrogen oxides containing gas with an aqueous slurry of calcium hydroxide.
It is necessary to use the aqueous slurry having high calcium hydroxide content such as 20 to 40 wt. %, whereby it is necessary to feed the gas having high nitrogen oxides concentration such as 5 to 12 vol. % to give high conversion to calcium nitrite. In order to prevent a formation of a by-product of calcium nitrate, a nitrogen oxides containing gas having 5 to 12 vol. % of a nitrogen oxides concentration and 1.5 to 2.5 of a molar ratio of NO/NO.sub.2 is fed under a high pressure enough to prevent a condensation of said slurry as a first stage and then, the unabsorbed gas is oxidized and the resulting gas having 1 to 5 vol. % of a nitrogen oxides concentration and 1.6 to 2.5 of molar ratio of NO/NO.sub.2 is fed to the aqueous slurry having 2 to 12 wt. % of a calcium hydroxide obtained in the first stage so as to convert the residual calcium hydroxide to calcium nitrite without forming a by-product of calcium nitrate. The process is carried out as continuous process having a first reaction zone and a second reaction zone.

REFERENCES:
patent: 4208391 (1980-06-01), Endo et al.

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