Process for producing an enamide

Details Process for producing an enamide Process for producing an enamide

1977-04-26

1979-01-30

Waltz, Thomas

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

252472, 26032613R, 260404, 260465D, 2604654, 260558R, 260558P, 260561R, 260562R, 260562P, 542421, 560 8, 560 20, 560 22, 560100, 560103, 560105, 560106, 560107, 560110, C07C10200, C07C 6700

Patent

active

041374177

ABSTRACT:
Enamides are prepared by hydrogenating oximes having at least one hydrogen atom at the .alpha.-position in the presence of a carboxylic anhydride using a ruthenium catalyst. These enamides are important to obtain amino group-containing compounds by reduction or polymerization.

REFERENCES:
patent: 4049584 (1977-09-01), Weissel
patent: 4055512 (1977-10-01), Kageyama et al.
Boar et al., Journal of the Chemical Society (1975), Perkin I, pp. 1237-1241.
Breitner et al., CA 54:3256f (1960).
Hartung et al., CA 48:115f (1952).
Theilheimer, Organic Syntheses, Abstract No. 40, vol. 14 (1958).
Albertson et al., J. Am. Chem. Soc., 70, 1150 (1948).
Hoy et al., J. Org. Chem., 23, 967 (1958).
Ferris et al., J. Org. Chem., 25, 492 (1960).

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