Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1986-11-24
1988-11-01
Ramsuer, Robert W.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
544141, 546145, 546322, 548351, 549439, 558413, 560142, 540483, 260349, C07C13900, C07D23910
Patent
active
047818662
ABSTRACT:
An efficient synthesis of quanidines, e.g. of the formula (III), by oxidizing a thiourea, e.g. of the following formula (II): ##STR1## with H.sub.2 O.sub.2 and a molybdenum catalyst to yield an aminoiminomethane sulfonic acid which can then be reacted with an amine followed by optional transamination steps.
REFERENCES:
patent: 4210658 (1980-07-01), Durant et al.
patent: 4265896 (1981-05-01), Durant et al.
patent: 4381395 (1983-04-01), Teraji et al.
Maryanoff Cynthia A.
Plampin James N.
Stanzione Robin C.
Levy David J.
McNeilab Inc.
Ramsuer Robert W.
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