Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...
Patent
1991-04-29
1992-07-21
Pal, Asok
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
By condensation of entire molecules or entire hydrocarbyl...
585 11, 585 24, 585 26, C07C 266
Patent
active
051324776
ABSTRACT:
The thermal and oxidative stability of HVI-PAO olefin oligomers is improved by reaction of the oligomerization mixture containing the olefin oligomer, dimer and isomerized but unoligomerized olefin with an aromatic compound such as toluene, xylene or naphthalene. The reaction is carried out in the presence of an acidic catalyst, which may be heterogeneous solid catalyst such as an acidic clay or a crystalline zeolite such as MCM-22, a homogeneous Friedel-Crafts catalyst such as AlCl.sub.3, BF.sub.3 or their complexes or a supported catalyst such as AlCl.sub.3 on graphite or silica. The reaction improves the yield and thermal stability of the lube range products. The olefinic oligomer mixture which is reacted with the aromatic compound is prepared from 1-alkene oligomerization in contact with a reduced metal oxide, preferably reduced chromium oxide, catalyst on support such as silica.
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Ho Suzzy C.
Pelrine Bruce P.
Wu Margaret M.
Keen Malcolm D.
McKillop Alexander J.
Mobil Oil Corporation
Pal Asok
Speciale Charles J.
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