Process for producing aliphatic polyester

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528272, 528297, 528361, 528503, 524783, C08G 6385

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active

056166818

ABSTRACT:
A method for producing an aliphatic polyester having a biodegradability and a higher melting point than conventional aliphatic polyester by suppressing a volatile component generated by side reaction or decomposition reaction with industrially good efficiency and economically in a relatively short period of time, the method enabling a polymerization at vacuum which permits a use of general vacuum pump. The aliphatic polyester can be obtained, for example, by a ring-opening copolymerization of a cyclic acid anhydride with a cyclic ether in a presence of a zirconium compound. The aliphatic polyester also can be obtained by performing a polymerization of raw materials of the aliphatic polyester so as to have a degree of viscosity in the range of 10-10,000 poise when 0.1-30 hours elapsed after the reaction started at reaction temperature of the reaction system under conditions of reaction temperature in the range of 180.degree. C. to 280.degree. C. and reaction pressure in the range of 0.3 mmHg to 3.0 mmHg.

REFERENCES:
patent: 3883901 (1975-05-01), Coquard et al.
patent: 5391700 (1995-02-01), Itoh et al.

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