Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1992-10-20
1993-08-24
Cintins, Marianne M.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560177, 568484, 568446, 568449, 568443, C07C 4541, C07C 6730, C07C 67327
Patent
active
052391086
ABSTRACT:
A process for producing an aliphatic or alicyclic aldehyde is disclosed, which process comprises the step of hydrogenating an aliphatic or alicyclic carboxylic acid or a derivative thereof with molecular hydrogen in the presence of a catalyst, wherein the catalyst is a zirconium oxide catalyst which contains chromium as an essential component, has a weakly basic site amount of more than 0.03 mmol/g as determined by a temperature programmed desorption method using carbon dioxide as an adsorbate in which the amount of carbon dioxide desorbed in the temperature range of from 100.degree. to 250.degree. C. is measured, and has pores having a radius of from 20 to 500 .ANG. in an amount of not less than 0.1 cc/g and pores having a radius of from 1,000 to 50,000 .ANG. in an amount of not less than 0.05 cc/g as measured with a mercury porosimeter. Aldehydes can be obtained directly from aliphatic or alicyclic carboxylic acids or derivatives thereof in high yield.
REFERENCES:
patent: 4613700 (1986-09-01), Maki et al.
Patent Abstracts of Japan, vol. 11, No. 192, abstract of JP-A-62 14 942.
Patent Abstracts of Japan, vol. 9, No. 317, abstract of JP-A-60 152 434.
Patent Abstracts of Japan, vol. 11, No. 322, abstract of JP-A-62 108 832.
Maki Takao
Matsuyama Naoko
Yokoyama Toshiharu
Cintins Marianne M.
Mitsubishi Kasei Corporation
Page Margaret J.
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