Process for producing alcohols and ketones

Details Process for producing alcohols and ketones Process for producing alcohols and ketones

1994-03-24

1995-06-20

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568320, 568321, 568399, 568815, 568836, 568910, C07C 4533

Patent

active

054262372

ABSTRACT:
The present invention provides a process for the oxidation of straight-chain, branched-chain or cyclic alkanes of 1-20 carbon atoms and benzene derivatives represented by the following formulas (1)-(2). The alcohols and ketones obtained by the oxidation of the alkanes mentioned above and those by the oxidation of the benzene derivatives mentioned above represented by the following formulas (3)-(6) are important as basic starting materials in producing various chemical products including resins, such as nylon and polyester, pharmaceuticals, agricultural chemicals, perfumes, dyes, etc. ##STR1##

REFERENCES:
patent: 3025306 (1962-03-01), Guest et al.
patent: 3483222 (1969-12-01), Sennewald et al.
patent: 3931330 (1976-01-01), Aprahamian
patent: 4341907 (1982-07-01), Zelonka
Galimor et al, Chem. Abst., vol. 108, #5421w (1988).
Murahashi et al, J.A.C.S., vol. 114, pp. 7913-7914 (1992).
Swern, et al; "Epoxidation of Oleic Acid, Methyl Oleate & Oleyl Alcohol with Perbenzoic Acid"; Am.Chem.Soc. (1944) vol. 66, 1925-27.
Swern, et al; "Chemistry of Epoxy Compounds.XII.1 Co-oxidation of Aldehydes and Oleic Acid, Methyl Oleate or Oleyl Alcohol", JACS, vol. 72, 4315-67, (1950).
Knopf, et al; "Oxirane durch Cooxidation von Alkenen und Aldehyden mit Sauerstoff" Synthesis (1944) 711-3.
Tsuchiya, et al.; "Liquid-phase Oxidation of 2-butene in the presence of Benzaldehyde" Canadian Journal of Chemistry, vol. 47, (1969) 3191-7.
Haber, et al; "Reactivity-Structure Correlations in Oxidation with Metalloporphyrins" Journal of Molecular Catalysis, vol. 52 (1989) 85-97.
Rogers et al.; "Iron Porphyrin catalysed Oxidation of Propanal and Cyclohexene by Molecular Oxygen" J. Chem. So., Chem. Commun, (1990) 1323-4.
Yamada et al; "Direct Epoxidation of Olefins Catalyzed by Nickel (II) Complexes with Molecular Oxygen and Aldehydes" Bull. Chem Soc. Jpn. (1991) vol. 64, 2109-2117.
Takai et al; "Aerobic Epoxidation of Olefinic Compounds Catalyzed by Tris (1,3-diketonato(iron(III)" Bull. Chem Soc Jap. (1991) vol. 64, 2513-8.
Kaneda et al; "Ruthenium-catalysed Oxidative Cleavage Reaction of Carbon-Carbon Double Bonds Using Molecular Oxygen" J.Chem. Soc., Chem. Commun., (1990) 1467-8.
Takai et al; "Aerobic Oxygenation of Olefinic Compounds into the Corresponding .alpha.-Hydroxy Ketones Using the Catalyst System of OsO4 and Ni(II)Complex" Chemistry Letters, (1991) 1499-1502.
Yamada et al; "The Baeyer-Villiger Oxidation of Ketones Catalyzed by Nickel(II)Complexes with Combined Use of Molecular Oxygen and an Aldehyde" Chemistry Letters (1991) 641-4.
S. A. Miller; "Cyclohexane, Cyclohenanol and Cyclohexanone", Chemical and Process Engineering, Jun. 1969, 50(6), 63-72.
Barton et al; "Functionalization of Saturated Hydrocarbons, Part 4, 1, The Gif System for Selective Oxidation using Molecular Oxygen" J.Chem. Soc.Perkin Trans I (1986) 947-955.

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