Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction
Patent
1983-11-28
1987-10-27
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
Liquid phase fischer-tropsch reaction
560232, 560263, 560265, C07C 2706, C07C 6700
Patent
active
047030640
ABSTRACT:
This invention relates to the manufacture of valuable alcohols containing 1 to 2 carbon atoms, especially ethylene glycol, methanol, and ethanol, from the reaction of hydrogen and carbon monoxide, by a homogeneous catalytic process using as the catalyst a synergistic mixture of solubilized ruthenium carbonyl complexes.
REFERENCES:
patent: 3833634 (1974-09-01), Pruett et al.
patent: 3855307 (1974-12-01), Rony et al.
patent: 4301253 (1981-11-01), Warren
patent: 4315993 (1982-02-01), Knifton
Fonseca et al., High Pressure Science & Technology, Sixth AIRAPT Conference, Plenum Press, N.Y. 1979, pp. 733-738.
Keim et al., J. of Catalysis, 61, 359-365 (1980).
Bradley, J.A.C.S., 10124 (1979), pp. 7419-7421.
Mars Howard T.
Trinker S. T.
Union Carbide Corporation
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