Process for producing adhesive tapes, in which adhesive...

Details Process for producing adhesive tapes, in which adhesive... Process for producing adhesive tapes, in which adhesive...

1999-09-30

2001-09-04

Pianalto, Bernard (Department: 1762)

Coating processes

Direct application of electrical, magnetic, wave, or...

Polymerization of coating utilizing direct application of...

C427S207100, C427S208200, C427S208400, C427S389900, C427S393500, C427S394000, C427S501000, C427S505000, C427S513000, C427S516000, C427S551000, C427S558000, C427S559000

Reexamination Certificate

active

06284328

ABSTRACT:

The invention relates to a process for producing adhesive tapes, in which adhesive tapes coated on one side with an adhesive composition are subjected to radiation crosslinking, and to their use.
It is known that, especially in the case of acrylates, the establishment of specific adhesion properties requires a crosslinking step. With rubbers, too, an improvement in adhesive performance, especially in respect of the cohesion, is achieved by crosslinking.
It is also known that, as the degree of crosslinking rises, the solubility of rubbers and acrylates in organic solvents is reduced.
However, the improvement in cohesion and solvent resistance following electron beam crosslinking (EB crosslinking) is frequently associated with a drastic reduction in bond strength and tack.
In the case of product developments, especially woven adhesive tapes, where solvent resistance is, a requirement in addition to acceptable bond strengths and unwind forces, this leads to considerable problems, to which to date there has been no satisfactory solution.
In the preparation of adhesive tapes, the use of radiation crosslinking, such as UV or EBC, suggests itself in addition to chemical/thermal crosslinking methods.
The dose/depth profile in a product irradiated on an electron beam unit is known for given acceleration voltages. Various authors have developed empirical functions to describe this profile (see, for example, Heger, beta-gamma 1, 20,1990 or Neuhaus-Steinmetz, RadTech Europe, Mediterraneo, 1993).
A basis used for the calculation of the radiation dose is, for example, the following empirical formula, which was published by Neuhaus-Steinmetz at RadTech Europe, Mediterraneo 1993.
D
⁡
[
%
]
=
exp
⁢
{
-
(
18.8
*
X
(
U
B
)
1.57
-
0.7
)
2
}
1
+
(
9.7
*
X
(
U
B
)
1.57
)
15
where
D is the dose in %
U
B
is the acceleration voltage in kV
X is the irradiated weight per unit area in g/m
2
, consisting of the weight per unit area of the vacuum window, the air gap between vacuum window and product, and the depth in the product
For products which consist of a coating to be irradiated, which may also be a pressure-sensitive adhesive, and a radiation-degradable backing, it is known to optimize the acceleration voltage. In this case the backing receives a significantly lower average dose than does the coating, while the dose reduction in the coating is still within an acceptable range for uniform crosslinking (Karmann, 7th Munich Adhesives and Finishing Seminar,1982; EP 0 453 254 (Yarosso et al.)).
In cable bandaging applications in the engine compartments of motor vehicles, based on adhesive tapes having a woven or nonwoven backing, petrol or diesel starts to dissolve the adhesive composition, as a result of which some of the adhesive composition migrates to the outside of the backing. Consequently, the cable bandaging becomes tacky on the outside and over time takes on considerable amounts of dirt.
The migration of partially dissolved adhesive composition to the other side of the backing can be suppressed by subjecting the adhesive composition to a high degree of crosslinking. As already mentioned, however, a degree of crosslinking which leads to sufficient insolubility in many cases entails inadequate bond strengths and unwind forces which do not meet the requirements of the application.
In practice, this deficiency is removed by the backing, in a first operation, receiving a coating which is highly crosslinked and so protects against the backing-side penetration of solvents, and by applying, in a second operation, a second layer of composition whose adhesion properties can be adjusted to the desired level by means of a freely selectable crosslinking. The crosslinking in this case is conducted, inter alia, with the aid of UV or electron beams. With the aid of crosslinking promoters, which are preferably added to the composition close to the backing, it is possible to ensure that the layer of composition close to the backing is crosslinked to a much higher degree, at a given UV or electron beam dose, than is the outer layer of composition. Radiation crosslinking can then be carried out in one pass for both compositions together.
Alternatively, the product properties can be adjusted if a first coating with subsequent irradiation at relatively high intensity is followed by a second coating with subsequent irradiation at lower intensity in one operation.
Both variants are extremely laborious and costly. Manufacture in one operation with two applicator units in series and a downstream irradiation unit, the first applicator unit applying a composition to which UV/EBC promoters have been added and the composition used in the second applicator unit lacking UV/EBC promoters, is highly demanding in terms of formulation and is virtually impossible to adapt to the planned applications.
A further disadvantage is that the radiation enters into the adhesive system from the side which is to be less highly crosslinked than the side facing the backing.
One example of an adhesive tape, based on a woven, for bandaging cable harnesses is disclosed in DE 44 19 169. The backing employed in this case is an open woven backing which is treated with inorganic phosphates or hydroxides and, if desired, with a coating material on the rear side. Coated onto the backing is a polar self-adhesive composition, treated with inorganic phosphates or hydroxides, which is of the acrylate or modified-rubber type and exhibits low solubility in nonpolar liquids.
The object of the invention is to remedy this situation and, in particular, to provide a process in which the disadvantages of the prior art are not present, or at least not to the same extent.
This object is achieved by a process as characterized more closely in the main claim. The subclaims describe advantageous embodiments of the process. Also embraced by the concept of the invention are adhesive tapes produced by the process of the invention, and the use of these adhesive tapes.
The invention accordingly provides a process for the radiation crosslinking of adhesive tapes coated on one side with an adhesive composition, the irradiation of the adhesive tape taking place through the backing material of the adhesive tape onto the adhesive composition in such a way that the backing material and that side of the adhesive composition facing the backing material receive a dose of from 30 to 200 kGy, in particular from 50 to 150 kGy, and, very particularly, 100 kGy, and the acceleration voltage during the irradiation being chosen such that the dose on the open side of the adhesive composition has fallen from 0 to 60 kGy, in particular from 0 to 50 kGy, and very particularly, from 10 to 20 kGy.
By this means it is ensured that, as a result of the high degree of crosslinking of the layer of composition on the side facing the backing, the migration of components of the composition to the open backing side cannot take place, while the adhesive properties of the tape are adjusted by way of the crosslinking in the region of the open composition side and also by way of the depth-related reduction in electron beam dose in the product.
The adhesive compositions employed are preferably acrylates, natural rubber systems, styrene block copolymers such as styrene-butadiene-styrene, styrene-isoprene-styrene or styrene-ethylene-butylene-styrene, in combination with tackifiers, from solution, from dispersion, or in the form of a hot melt.
In addition, the adhesive compositions can be filled, coloured and/or foamed.
Preference is also given to open backing materials such as, for example, nonwovens, spunbondeds or wovens made from PP, PE, polyester, or other polymers or copolymers customary for the application. The woven backing is, in particular, a viscose staple woven or cotton woven, or a polyester woven.
The process of the invention permits, inter alia, the cost-effective production of an adhesive tape having a woven or nonwoven backing for cable bandaging applications or for applications in engine compartments in motor vehicles, which suffers no adverse consequences whatsoever from petrol or diesel

Affiliated with

Also associated with

Rating

Process for producing adhesive tapes, in which adhesive... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for producing adhesive tapes, in which adhesive..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for producing adhesive tapes, in which adhesive... will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2517308