Process for producing acetic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 5112

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active

053449720

ABSTRACT:
There is disclosed a process for producing acetic acid in which methyl formate is isomerized into acetic acid with a catalyst containing at least one of Pd, Ru and Ir, at least one compound of said metals or a mixture thereof, and a promoter of a halide compound in the presence of carbon monoxide. This process can be carried out under mild reaction conditions and acetic acid is obtained in high yield.

REFERENCES:
patent: Re29981 (1979-05-01), Isogai
patent: 3839428 (1974-10-01), Isogai
patent: 4194056 (1980-03-01), Antoniades
Roth et al, Low Pressure Process for Acetic Acid via Carbonylation, Chem. Tech., Oct. 1971, pp. 600-605.
Fenton et al, Noble Metal Ions.revreaction.Noble Catalysts, Chem. Tech., Apr. 1972, pp. 220-225.

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