Process for producing ABS resins

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C08F27904

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041419332

ABSTRACT:
A process for producing ABS resins by copolymerizing a mixture of a styrenic compound and an unsaturated nitrile selected from the group consisting of acrylonitrile and methacrylonitrile, in the presence of an elastomer, by a two-step process comprising a mass copolymerization step and then a suspension copolymerization step, said process comprising carrying out the mass copolymerization step in the presence of p-chlorobenzoyl peroxide as an initiator and dithiobis(benzothiazole) as a chain transfer agent.

REFERENCES:
patent: 2754290 (1956-07-01), Kern
patent: 3373227 (1968-03-01), Finestone
patent: 3551523 (1970-12-01), Killoran
R. J. Kern, J. Am. Chem. Soc. 77, 1382-1383, 1955.

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