Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...
Patent
1993-12-20
1995-07-25
Achutamurthy, P.
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
By condensation of entire molecules or entire hydrocarbyl...
585438, 585453, 585463, 585467, C07C 272
Patent
active
054363810
ABSTRACT:
There is disclosed a process for producing a monoalkenylbenzene which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst produced by calcining the mixture of potassium hydroxide and aluminum hydroxide and then heat treating the calcined product together with metallic sodium in an atmosphere of an inert gas. According to the aforesaid process, an industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety.
REFERENCES:
patent: 3244758 (1966-04-01), Eberhardt
patent: 3928485 (1975-12-01), Nagase et al.
patent: 4511748 (1985-04-01), Kudoh et al.
patent: 4990717 (1991-02-01), Sikkenga et al.
Chemical Abstracts, vol. 119, No. 13, 27 Sep. 1993, p. 836, abstract No. 138842h, Columbus, Ohio, U.S. of JP 5 112 476.
Fushimi Norio
Kato Kinji
Kedo Ko
Takagawa Makoto
Achutamurthy P.
Mitsubishi Gas Chemical Company Inc.
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