Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing
Reexamination Certificate
2007-04-24
2007-04-24
Parsa, J. (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Halogen containing
C570S140000
Reexamination Certificate
active
11370985
ABSTRACT:
The present invention provides a process for producing 4-(2-methylphenyl)benzotrifluoride, comprising reacting 4-chlorobenzotrifluoride with 2-methylphenylmagnesium chloride in the presence of cobalt-based catalyst and zinc salt.
REFERENCES:
patent: 2001/0020110 (2001-09-01), Shintaku et al.
patent: 2001/0034459 (2001-10-01), Meudt et al.
A. Indolese, “Suzuki-Type Coupling of Chloroarenes with Arylboronic Acids Catalysed by Nickel Complexes”, Tetrahedron Letters, vol. 38, No. 20, (1997), pp. 3513-3516.
T. Korn et al., “New Colbalt-Catalyzed Cross-Coupling Reactions of Heterocyclic Chlorides with Aryl and Heteroaryl Magnesium Halides”, SYNLETT 2003, No. 12, pp. 1892-1894.
Gilber R. Rosa, et al. “A Superior Non-Symmetrical NCP Pincer Type Palladacycle Catalyst Precursor for the Coupling of Aryl Boronic Acids with Aryl Chlorides”, Synthesis, Georg Thieme Verlag, Stuttgart, DE, No. 18, Dec. 18, 2003, pp. 2894-2897.
Sugi Kiyoshi
Tanaka Masahide
Parsa J.
Sumitomo Chemical Company Limited
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